29. Mechanism of Z-Selective Allylic Functionalization via Thianthrenium Salts
Targos, K.; Gogoi, A.R.; Rentería-Gómez, A.; Kim, M.J.; Gutierrez, O.*; Wickens, Z.K*.
J. Am. Chem. Soc. 2024, 146, 20, 13689–13696.
28. Alkene Thianthrenation Unlocks Diverse Cation Synthons: Recent Progress and New Opportunities
Kim, M.J.†; Targos, K.†; Holst, D.E.; Wang, D.J.; Wickens, Z.K.*
Angew. Chem. Int. Ed. 2024, e202314904.
27. Ketyl Radical Coupling Enabled by Polycyclic Aromatic Hydrocarbon Electrophotocatalysts
Edgecomb, J.M.; Alektiar, S.N.; Cowper, N.G.; Sowin, J.A.; Wickens, Z.K.*
J. Am. Chem. Soc. 2023, 145, 37, 20169–20175.
Highlight in ACS Journal: 10 Chemistry Articles Everyone Was Reading in September 2023.
Highlight in Synfacts 2023: Electrocatalytic Generation of Unstabilized Ketyl Radicals and their Coupling to Alkenes.
26. Rethinking catalyst design by using data science
Alektiar, S.N.; Wickens, Z.K.*
Chem. 2023, 9, 1–3.
25. Radical Hydrocarboxylation of Unactivated Alkenes via Photocatalytic Formate Activation
Alektiar, S.N.†; Han, J.†; Dang, Y; Rubel, C.Z.; Wickens, Z.K.*
J. Am. Chem. Soc. 2023, 145, 20, 10991–10997.
OPR&D Highlight Some Items of Interest to Process R&D Chemists and Engineers July 2023.
24. Regiospecific Alkene Aminofunctionalization via an Electrogenerated Dielectrophile
Holst, D.E.; Dorval, C.; Winter, C.K.; Guzei, I.A.; Wickens, Z.K.*
J. Am. Chem. Soc. 2023, 145, 15, 8299–8307.
23. Diastereoselective Synthesis of Cyclopropanes from Carbon Pronucleophiles and Terminal Alkenes
Kim, M.J.; Wang, D.J.; Targos, K.; Garcia, U.A.; Harris, A.F.; Guzei, I.A.; Wickens, Z.K.*
Angew. Chem. Int. Ed. 2023, e202303032.
OPR&D Highlight Some Items of Interest to Process R&D Chemists and Engineers June 2023.
22. Practical and General Alcohol Deoxygenation Protocol
Angew. Chem. Int. Ed. 2023, e202300178.
OPR&D Highlight Some Items of Interest to Process R&D Chemists and Engineers May 2023.
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21. Translating planar heterocycles into 3D analogs via photoinduced hydrocarboxylation
Mikhael, M.; Alektiar, S.N.; Yeung, C.; Wickens, Z.K.*
Angew. Chem. Int. Ed. 2023, e202303264.
20. An alkene, a photon, and a catalyst walk into a bar; Zaitsev wasn’t invited
Alektiar, S.N.; Williams, O.P.; Wickens, Z.K.*
Trends in Chemistry 2022, 4 (6), 467–470.
19. Electrochemical Synthesis of Allylic Amines from Alkenes and Amines
Wang, D. J.; Targos, K.; Wickens, Z.K.*
J. Am. Chem. Soc. 2021, 143, 21503–21510.
Org. Chem. Highlight Org. Chem. Highlights 2022, May 23
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18. Photoinduced Hydrocarboxylation via Thiol-Catalyzed Delivery of Formate Across Alkenes
Alektiar, S. N.; Wickens, Z. K.*
J. Am. Chem. Soc. 2021, 143, 33, 13022–13028.
Synfacts highlight Synfacts 2021; 17(11): 1261
JACS Spotlight J. Am. Chem. Soc. 2021, 143, 37, 14937–14938
ORPD Items of Interest highlight Org. Process Res. Dev. 2021, 25, 10, 2155–2166
17. Aziridine synthesis by coupling amines and alkenes via an electrogenerated dication
Holst, D. E.†; Wang, D. J.†; Kim, M.; Guzei, I. A.; Wickens, Z. K.*
Nature 2021, 596, 74–79.
Highlighted by T. Piou and LC. Campeau Nat. Chem. 13, 1027–1028 (2021)
Synthesis Workshop Highlight
Synfacts highlight Synfacts 2022; 18(02): 0125
16. Non-Innocent Radical Ion Intermediates in Photoredox Catalysis: Parallel Reduction Modes Enable Coupling of Diverse Aryl Chlorides
Chmiel, A. F.; Williams, O. P.; Chernowsky, C. P.; Yeung, C.; Wickens, Z. K.*
J. Am. Chem. Soc. 2021, 143, 10882–10889.
Synthesis Workshop highlight
15. Electrochemical Activation of Diverse Conventional Photoredox Catalysts Induces New Potent Photoreductant Activity
Chernowsky, C. P.; Chmiel, A. F.; Wickens, Z. K.*
Angew. Chem. Int. Ed. 2021, 60 (39), 21418–21425.
14. Unveiling Potent Photooxidation Behavior of Catalytic Photoreductants
Targos, K. T.†; Williams, O. P.†; Wickens, Z. K.*
J. Am. Chem. Soc. 2021 143, 11, 4125–4132.
13. Potent Reductants via Electron-Primed Photoredox Catalysis: Unlocking Aryl Chlorides for Radical Coupling
Cowper, N. G. W.†; Chernowsky, C. P.†; Williams, O. P.; Wickens, Z. K.*
J. Am. Chem. Soc. 2020 142, 2093–2099
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Prior to Wisconsin
12. A Case Study in Catalyst Generality: Simultaneous, Highly-Enantioselective Brønsted- and Lewis-Acid Mechanisms in Hydrogen-Bond-Donor Catalyzed Oxetane Openings.
Strassfeld, D. A.; Algera, R. F.; Wickens, Z. K.; Jacobsen, E. N.
J. Am. Chem. Soc. 2021, 143, 9585–9594
11. Highly Enantioselective, Hydrogen-Bond-Donor Catalyzed Additions to Oxetanes
Strassfeld, D. A.; Wickens, Z. K.; Picazo, E.; Jacobsen, E. N.
J. Am. Chem. Soc. 2020, 142, 9175-9180.
10. Direct Access to β-Fluorinated Aldehydes by Nitrite-Modified Wacker Oxidation
Chu, C.K.; Ziegler, D.T.; Carr, B.; Wickens, Z.K.; Grubbs R.H.*
Angew. Chem. Int. Ed. 2016, 55, 8435 – 8439
9. Tandem Z-selective Cross Metathesis-Dihydroxylation for the Synthesis of anti-1,2-Diols
Dornan, P.; Wickens, Z. K.; Grubbs, R. H.*
Angew. Chem. Int. Ed. 2015, 54, 7134 – 7138.
8. Aerobic Palladium-Catalyzed Diacetoxylation of Alkenes Enabled by Catalytic Nitrite
Wickens, Z. K.; Guzman, P.; Grubbs, R. H.*
Angew. Chem. Int. Ed. 2015, 54, 236 – 240.
7. Rapid Access to alpha-Trifluoromethyl-Substituted Ketones: Harnessing Inductive Effects in Wacker-Type Oxidations of Internal Alkenes
Lerch, M.; Morandi, B.; Wickens, Z. K.; Grubbs, R. H.*
Angew. Chem. Int. Ed. 2014, 53, 8654 – 8658.
6. Catalyst-Controlled Wacker-Type Oxidation: Facile Access to Functionalized Aldehydes
Wickens, Z. K.; Skakuj, K.§; Morandi, B.; Grubbs, R. H.*
J. Am. Chem. Soc. 2014, 136, 890–893.
5. Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst
Wickens, Z. K.; Morandi, B.; Grubbs, R. H.*
Angew. Chem. Int. Ed. 2013, 52, 11257 – 11260.
4. Regioselective Wacker Oxidation of Internal Alkenes: Rapid Access to Functionalized Ketones Facilitated by Cross-Metathesis
Morandi, B; Wickens, Z. K.; Grubbs, R. H.*
Angew. Chem. Int. Ed. 2013, 52, 9751–9754.
3. Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins
Morandi, B.; Wickens, Z. K.; Grubbs, R. H.*
Angew. Chem. Int. Ed. 2013, 52, 11257 – 11260.
2.Efficient and Highly Aldehyde Selective Wacker Oxidation
Teo, P.; Wickens, Z. K.; Dong, G.; Grubbs, R. H.*
Org. Lett. 2012, 14, 3237.
1. Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis
Dong, G.; Teo, P.†; Wickens, Z. K.†; Grubbs, R. H.*
Science, 2011, 333, 1609.